A KINETIC-STUDY ON MMA BULK RADICAL POLYMERIZATION

被引：21

作者：

SHEN, JC

WANG, GB

YANG, ML

ZHENG, YG

机构：

[1] Department of Chemistry, Jilin University, Changchun

来源：

POLYMER INTERNATIONAL | 1992年 / 28卷 / 01期

关键词：

RADICAL POLYMERIZATION; NONEQUAL REACTIVITY; MICRO-SURROUNDINGS; MICRO-DIFFUSION; WRAPPING EFFECT;

D O I：

10.1002/pi.4990280113

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The nonequalities of the reactivity and the micro-environment of propagating radicals has been found in MMA bulk polymerization.This nonequal reactivity results from varying rates or diffusion in different micro-surroundings. The decrease of radical reactivity is caused by the trapping of the segments around the propagating radical.

引用

页码：75 / 79

页数：5

共 13 条

[1]

Bamford CH, 1958, KINETICS VINYL POLYM, P111

[2] HIGH-CONVERSION POLYMERIZATION .1. THEORY AND APPLICATION TO METHYL-METHACRYLATE [J].