ELECTROCHEMICAL ENHANCEMENT OF OXIDATIVE COUPLING OF METHANE OVER LiCl-DOPED NiO USING STABILIZED ZIRCONIA ELECTROLYTE

被引：39

作者：

Otsuka, Kyoshi ^{[1
]}

Suga, Katsuo ^{[1
]}

Yamanaka, Ichiro ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem Engn, Meguro Ku, Tokyo 152, Japan

来源：

CATALYSIS LETTERS | 1988年 / 1卷 / 12期

关键词：

D O I：

10.1007/BF00766201

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxidative coupling of methane into ethylene and ethane over LiCl-doped NiO was enhanced when oxygen was pumped electrochemically to the catalyst through a stabilized zirconia oxygen-anion conductor. This favourable effect can be ascribed to the generation of reactive oxygen species on the catalyst for selective synthesis of C-2 compounds.

引用

页码：423 / 428

页数：6

共 7 条

[1] BAERNS M, 1987, CATAL TODAY, V1, P357
[2] SYNTHESIS OF ETHYLENE BY PARTIAL OXIDATION OF METHANE OVER THE OXIDES OF TRANSITION-ELEMENTS WITH LICL
OTSUKA, K
LIU, Q
HATANO, M
MORIKAWA, A
[J]. CHEMISTRY LETTERS, 1986, (06) : 903 - 906
[3] CATALYTIC ACTIVITY-CONTROL AND SELECTIVITY-CONTROL FOR OXIDATIVE COUPLING OF METHANE BY OXYGEN-PUMPING THROUGH YTTRIA-STABILIZED ZIRCONIA
OTSUKA, K
YOKOYAMA, S
MORIKAWA, A
[J]. CHEMISTRY LETTERS, 1985, (03) : 319 - 322
[4] Otsuka K., 1988, CATAL TODAY IN PRESS
[5] Otsuka K., 1987, SEKIYU GIAKKAISHI, V30, P385
[6] THE EFFECT OF ELECTROCHEMICAL OXYGEN PUMPING ON THE RATE AND SELECTIVITY OF ETHYLENE OXIDATION ON POLYCRYSTALLINE SILVER
STOUKIDES, M
VAYENAS, CG
[J]. JOURNAL OF CATALYSIS, 1981, 70 (01) : 137 - 146
[7] Ueda W., 1988, J CHEM SOC CHEM COMM, P1145

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