SYNTHESIS OF OPTICALLY-ACTIVE TELLURIUM-CONTAINING BINAPHTHYLS AND THEIR USE IN THE ASYMMETRIC 1,4-ADDITION REACTION OF ALPHA,BETA-UNSATURATED KETONES

被引：10

作者：

IRIE, M ^{[1
]}

DOI, Y ^{[1
]}

OHSUKA, M ^{[1
]}

ASO, Y ^{[1
]}

OTSUBO, T ^{[1
]}

OGURA, F ^{[1
]}

机构：

[1] HIROSHIMA UNIV,FAC ENGN,DEPT APPL CHEM,HIGASHIHIROSHIMA 724,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 10期

关键词：

D O I：

10.1016/S0957-4166(00)80056-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel tellurium-containing binaphthyls have been prepared in optically active form and used as chiral inducers in the asymmetric 1,4-addition reactions of alpha,beta-unsaturated ketones with aluminium arenetellurolate.

引用

页码：2127 / 2130

页数：4

共 15 条

[1] PREPARATION AND LITHIATION OF OPTICALLY-ACTIVE 2,2'-DIHALO-1,1'-BINAPHTHYLS - A GENERAL STRATEGY FOR OBTAINING CHIRAL, BIDENTATE LIGANDS FOR USE IN ASYMMETRIC-SYNTHESIS [J].

BROWN, KJ ;

BERRY, MS ;

WATERMAN, KC ;

LINGENFELTER, D ;

MURDOCH, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (17) :4717-4723

[2] ASYMMETRIC OXYSELENENYLATION OF OLEFINS USING OPTICALLY-ACTIVE SELENOBINAPHTHYLS AND D-MENTHOL AS A NUCLEOPHILE [J].

FUJITA, K ;

IWAOKA, M ;

TOMODA, S .

CHEMISTRY LETTERS, 1992, (07) :1123-1124

[3]

Irgolic K.J., 1990, ORGANOTELLURIUM COMP

[4]

KLAYMANN D, 1991, SYNTHESIS-STUTTGART, P793

[5] BINAP - AN EFFICIENT CHIRAL ELEMENT FOR ASYMMETRIC CATALYSIS [J].

NOYORI, R ;

TAKAYA, H .

ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (10) :345-350

[6]

OTSUKA S, 1991, SYNTHESIS-STUTTGART, P665

[7]

PETRAGNANI N, 1986, SYNTHESIS-STUTTGART, P1

[8]

ROSINI C, 1992, SYNTHESIS-STUTTGART, P503

[9] ORGANOTELLURIUMS .17. 1,4-ADDITION OF DIISOBUTYLALUMINUM BENZENETELLUROLATE TO ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS AND ALDOL REACTION OF RESULTING ALUMINUM ENOLATES [J].

SASAKI, K ;

ASO, Y ;

OTSUBO, T ;

OGURA, F .

CHEMISTRY LETTERS, 1989, (04) :607-610

[10] STEREOCHEMICAL STUDIES OF THE HYDROGENATION WITH AN ASYMMETRICALLY MODIFIED RANEY-NICKEL CATALYST - THE HYDROGENATION OF ACETYLACETONE [J].

TAI, A ;

ITO, K ;

HARADA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (01) :223-227

← 1 2 →