CHEMISTRY OF HETEROCYCLIC-COMPOUNDS .36. REDUCTION REACTIONS OF PYRIDYL KETONES WITH LOW VALENT TITANIUM REAGENTS

被引：29

作者：

NEWKOME, GR

ROPER, JM

机构：

[1] Department of Chemistry, Louisiana State University, Louisiana 70803, Baton Rouge

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 04期

关键词：

D O I：

10.1021/jo01318a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pyridyl ketones react with low valent titanium reagents, generated either by LiAlH4 and TiCI3 or Na0 and TiCI3, to give either the corresponding alcohol or the reductively coupled products. The olefinic products generally arise when intramolecular N-complexation of the titanium ions is prevented, and ill-defined polymeric material is formed when two sites of potential complexation are available. © 1979, American Chemical Society. All rights reserved.

引用

页码：502 / 505

页数：4

共 27 条

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