THE PROTONATION OF BRIDGING DINITROGEN TO YIELD AMMONIA

被引：52

作者：

LEIGH, GJ

PRIETOALCON, R

SANDERS, JR

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 14期

关键词：

TANTALUM DITHIOCARBAMATO-COMPLEXES; HYDRAZINE-FORMING REACTIONS; MECHANISM; CHEMISTRY; KINETICS; NIOBIUM;

D O I：

10.1039/c39910000921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The protonation of the V(II) bridging dinitrogen complex [{V(C6H4CH2NMe2)2(C5H5N)}2N2] yields 2/3NH3, 2/3N2 and unidentified V(III)-containing products, although hydrazine might have been expected on the basis of its structure; another factor influencing the product of dinitrogen protonation appears to be the availability of electrons from the metal atoms.

引用

页码：921 / 922

页数：2

共 14 条

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