COBALT(I)-PHTHALOCYANINE ANION AS VITAMIN-B12S MODEL - SELECTIVITY IN REACTIONS WITH ELECTROPHILES

被引：11

作者：

ECKERT, H

SCHIER, A

机构：

[1] Organisch-Chemisches Institut, Technischen Universität München, Garching, D-8046

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1979年 / 18卷 / 10期

关键词：

D O I：

10.1002/anie.197907941

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In order to understand vitamin B12S‐catalyzed reactions and to ascertain the synthetic scope of the only “supernucleophile” storable at room temperature, [Co1Pc]−, it is necessary to know the selectivity of this anion towards functional groups. In its selective behavior, [Co1Pc]− resembles nucleophiles such as I− but is much more reactive. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：794 / 796

页数：3

共 16 条

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