SYNTHESIS AND STRUCTURE OF CHIRAL METAL-COMPLEXES OF POLYAZACYCLOALKANE LIGANDS INCORPORATING PHOSPHINIC ACID DONORS

被引：38

作者：

COLE, E

PARKER, D

FERGUSON, G

GALLAGHER, JF

KAITNER, B

机构：

[1] UNIV DURHAM, DEPT CHEM, SOUTH RD, DURHAM DH1 3LE, ENGLAND

[2] UNIV GUELPH, DEPT CHEM, GUELPH N1G 2W1, ONTARIO, CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 20期

关键词：

D O I：

10.1039/c39910001473

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chiral copper(II) and gallium(III) complexes of a triazatris(phenylphosphinic acid) ligand have very similar structures: the anionic copper complex possesses C3 symmetry, shows no Jahn-Teller distortion at 293 K nor at 123 K and is resistant to protonation.

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页码：1473 / 1475

页数：3

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