ELECTROCHEMICAL AND OPTICAL-PROPERTIES OF POLY(3-METHYLTHIOPHENES) ELECTROSYNTHESIZED BY 3,3'-4,4'-DIMETHYL-2,2'-BITHIOPHENES, 3,4'-4,4'-DIMETHYL-2,2'-BITHIOPHENES AND 4,4'-DIMETHYL-2,2'-BITHIOPHENES

被引:36
作者
ARBIZZANI, C [1 ]
BARBARELLA, G [1 ]
BONGINI, A [1 ]
MASTRAGOSTINO, M [1 ]
ZAMBIANCHI, M [1 ]
机构
[1] CNR,ICOCEA,I-40064 OZZANO EMILIA,ITALY
关键词
D O I
10.1016/0379-6779(92)90032-E
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The 3,3'-, 3,4'- and 4,4'-dimethyl-2,2'-bithiophenes, prepared in very pure form and characterized by C-13 NMR, were used as starting molecules for electrochemical polymerization of poly(3-methylthiophenes). The optical properties of the resulting polymers were interpreted on the basis of the conformation of the starting dimers determined by force field MMP2 calculations.
引用
收藏
页码:329 / 339
页数:11
相关论文
共 14 条