CATECHOLATES AS SIGMA-DONATING AND PI-DONATING LIGANDS - THE SYNTHESIS AND STRUCTURE OF (ET4N)2[W(CO)4(O2C6H4)] AND THE 16 ELECTRON ANALOG RESULTING FROM CO DISSOCIATION
被引:31
作者:
DARENSBOURG, DJ
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机构:Department of Chemistry, Texas A & M University, College Station, Texas
DARENSBOURG, DJ
KLAUSMEYER, KK
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机构:Department of Chemistry, Texas A & M University, College Station, Texas
KLAUSMEYER, KK
MUELLER, BL
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机构:Department of Chemistry, Texas A & M University, College Station, Texas
MUELLER, BL
REIBENSPIES, JH
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机构:Department of Chemistry, Texas A & M University, College Station, Texas
REIBENSPIES, JH
机构:
[1] Department of Chemistry, Texas A & M University, College Station, Texas
来源:
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH
|
1992年
/
31卷
/
11期
关键词:
D O I:
10.1002/anie.199215031
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Alkoxo ligands with strong pi-donor character stabilize coordinatively unsaturated organometallic compounds. This is confirmed by the two complexes 2 (each formally 16-electron species), which are in equilibrium with the starting materials When R = tBu, 1 exists in the pure state only under a CO atmosphere, and 2 can even be characterized by X-ray crystallography. R = H, tBu.