恩洪向斜煤层重烃浓度异常及其成因

被引:0
作者
兰凤娟
机构
[1] 中国矿业大学
关键词
煤层; 重烃气浓度; 异常; 有机热降解; 地质因素;
D O I
暂无
年度学位
2013
学位类型
博士
导师
摘要
针对恩洪向斜上二叠统煤层重烃浓度异常原因这一长期争议纷纭的科学问题,从煤层气成藏条件、气体同位素、生烃母质、流体活动、孔隙特征等方面开展研究,取得某些新的认识: 1)发现恩洪向斜部分地区煤层重烃浓度高度异常,在垂向上具有“半旋回”特征,在区域上成片集中分布,地下水头高度与重烃浓度异常区分布一致,认为重烃浓度垂向分布特征受沉积序列控制,向斜构造对煤层重烃起到了强烈的封闭作用,地下水活动是控制煤层重烃浓度高低的一个重要地质因素。 2)根据煤层自然解吸气烃类、二氧化碳的碳同位素和氦同位素组成分析,认为恩洪煤层重烃气形成于有机热成因,煤层重烃浓度差异的主要原因在于受地下水活跃程度影响的微生物作用强弱,微生物降解重烃的过程具有选择性,使得所产生的甲烷富集12C,碳同位素较重的母质能产生较多的重烃和二氧化碳。 3)基于生烃热模拟实验和煤岩学分析,发现无论煤层重烃浓度正常区还是异常区,煤样的生烃母质组成和类型、生烃量、烃类组成没有实质性差别,均能够产生大量重烃;重烃气的产生贯穿于整个热模拟过程,直到模拟末期(热解温度500℃)重烃气产出量仍大于甲烷产出量。 4)煤及其脉体流体包裹体观测揭示,恩洪向斜煤层发育大量生油标志,指示该区煤生油能力较强,并发生过显著的生油历史,说明煤层重烃气浓度异常与生油能力之间存在必然联系。重烃浓度正常区与异常区煤中树皮体含量差别显著,渗出沥青体与树皮体在产状上存在成因联系,指示煤层重烃气主要来源于树皮体。 5)发现煤及含煤地层方解石脉体油气包裹体极为发育,重烃浓度正常区流体包裹体均一温度集中在130~150℃之间,异常区包裹体均一温度集中在80~90℃和100~110℃两个区间,即异常区煤中有机质经历了完整的“生油窗”,这可能是其煤层重烃气浓度显著较高的一个重要地质原因。
引用
收藏
页数:192
共 129 条
[1]
Secondary biogenic coal seam gas reservoirs in New Zealand: A preliminary assessment of gas contents.[J].Carol I. Butland;Tim A. Moore.International Journal of Coal Geology.2008, 1
[2]
Coalbed methane producibility from the Mannville coals in Alberta; Canada: A comparison of two areas.[J].T. Gentzis;F. Goodarzi;F.K. Cheung;F. Laggoun-Défarge.International Journal of Coal Geology.2008, 3
[3]
Comparison of hydrocarbon gases (C 1 –C 5 ) production from Carboniferous Donets (Ukraine) and Cretaceous Sabinas (Mexico) coals.[J].D. Alsaab;M. Elie;A. Izart;R.F. Sachsenhofer;V.A. Privalov;I. Suarez-Ruiz;L. Martinez.International Journal of Coal Geology.2007, 2
[4]
Enhanced late gas generation potential of petroleum source rocks via recombination reactions: Evidence from the Norwegian North Sea [J].
Erdmann, Michael ;
Horsfield, Brian .
GEOCHIMICA ET COSMOCHIMICA ACTA, 2006, 70 (15) :3943-3956
[5]
Secondary biological coalbed gas in the Xinji area; Anhui province; China: Evidence from the geochemical features and secondary changes.[J].Mingxin Tao;Baoguang Shi;Jinying Li;Wanchun Wang;Xiaobin Li;Bo Gao.International Journal of Coal Geology.2006, 2
[6]
Carbon isotopic fractionation of CH 4 and CO 2 during canister desorption of coal.[J]..Organic Geochemistry.2005, 2
[7]
The analysis of oil trapped during secondary migration.[J].Simon C. George;Manzur Ahmed;Keyu Liu;Herbert Volk.Organic Geochemistry.2004, 11
[8]
Fluid inclusion evidence for an early, marine-sourced oil charge prior to gas-condensate migration, Bayu-1, Timor Sea, Australia [J].
George, SC ;
Lisk, M ;
Eadington, PJ .
MARINE AND PETROLEUM GEOLOGY, 2004, 21 (09) :1107-1128
[9]
Adsorption of petroleum compounds in vitrinite: implications for petroleum expulsion from coal.[J]..International Journal of Coal Geology.2004, 3
[10]
Application of Rank(Sr), a maturity index based on chemical analyses of coals [J].
Suggate, RP .
MARINE AND PETROLEUM GEOLOGY, 2002, 19 (08) :929-950