ON THE ORIGIN OF PI-FACIAL DIASTEREOSELECTIVITY IN NUCLEOPHILIC ADDITIONS TO CHIRAL CARBONYL-COMPOUNDS .3. ROTATIONAL PROFILES OF 2-METHOXYPROPANAL AND 2-N,N-DIMETHYLAMINOPROPANAL

被引：23

作者：

FRENKING, G ^{[1
]}

KOHLER, KF ^{[1
]}

REETZ, MT ^{[1
]}

机构：

[1] MAX PLANCK INST COAL RES,W-4330 MULHEIM,GERMANY

来源：

TETRAHEDRON | 1993年 / 49卷 / 19期

关键词：

D O I：

10.1016/S0040-4020(01)89911-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rotational profiles of 2-methoxypropanal and 2-N,N-dimethylaminopropanal are theoretically predicted using ab initio methods at the MP2/6-31G*//3-21G level of theory. The conformational energies show a strong dependence on the torsion angle not only around the C-C bond but also around the C-R (R=OMe, NMe2) bond.

引用

页码：3971 / 3982

页数：12

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