MAGNESIUM ALCOHOLATES AS PRECURSORS FOR MAGNESIA

被引：48

作者：

THOMS, H

EPPLE, M

VIEBROCK, H

RELLER, A

机构：

[1] Inorganic and Applied Chemistry Institute, University of Hamburg, D-20146 Hamburg

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 04期

关键词：

D O I：

10.1039/jm9950500589

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis, structural aspects and thermal behaviour of six different magnesium alcoholates are reported. The magnesium oxides obtained by decomposition of the alkoxides show different particle morphologies, as shown by scanning electron microscopy. The mechanism of the thermal decomposition of magnesium methanolate was studied in detail. The substance decomposed in three steps at 90, 330-350 and 360-400 degrees C. Two intermediates were characterized by elementary analysis (C, H) and IR spectroscopy.

引用

页码：589 / 594

页数：6

共 17 条

[1] COMPOSITION OF GRIGNARD COMPOUNDS .10. NMR, IR, AND MOLECULAR ASSOCIATION STUDIES OF SOME METHYLMAGNESIUM ALKOXIDES IN DIETHYL-ETHER, TETRAHYDROFURAN, AND BENZENE [J].