NOVEL SYNTHESIS OF A CHIRAL CYCLIC DIENEDIYNE SYSTEM RELATED TO THE NEOCARZINOSTATIN CHROMOPHORE

被引：31

作者：

NAKATANI, K ^{[1
]}

ARAI, K ^{[1
]}

TERASHIMA, S ^{[1
]}

机构：

[1] SAGAMI CHEM RES CTR,NISHI OHNUMA,SAGAMIHARA,KANAGAWA 229,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 04期

关键词：

D O I：

10.1039/c39920000289

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By successive treatment with lithium bistrimethylsilylamide and boron trifluoride-diethyl ether in tetrahydrofuran at -78-degrees-C optically active (Z)-dienediyne epoxide 20 prepared from D-xylose and (Z)-enol triflate 16 is found to undergo smooth cyclization to afford the title compound.

引用

页码：289 / 291

页数：3

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