TRIS(TRIMETHYLSILYL) TITANACYCLOBUTENE - A NEW MILD REAGENT FOR THE CONVERSION OF CARBONYLS TO ALKENYL SILANES

被引：40

作者：

PETASIS, NA

STASZEWSKI, JP

FU, DK

机构：

[1] Department of Chemistry, University of Southern California, Los Angeles

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 21期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(95)00579-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thermolysis of Cp(2)Ti(CH(2)SiMe(3))(2) in the presence of Me(3)SiC=CSiMe(3) forms tris(trimethylsilyl) titanacyclobutene. Unlike other titanacyclobutenes which undergo insertion with carbonyl compounds, this reagent serves as a precursor to Cp(2)Ti=CHSiMe(3), converting carbonyl compounds to the corresponding alkenyl silanes. This olefination takes place under mild conditions even at room temperature and works with aldehydes, ketones, esters, thioesters and lactones.

引用

页码：3619 / 3622

页数：4

共 26 条

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