BONDING AND ENERGETICS OF PHOSPHORUS(III) LIGANDS IN TRANSITION-METAL COMPLEXES

被引：137

作者：

DIAS, PB

DEPIEDADE, MEM

SIMOES, JAM

机构：

[1] Univ Tecn Lisboa, CTR QUIM ESTRUTURAL, INST SUPER TECN, P-1096 LISBON, PORTUGAL

[2] Univ Tecn Lisboa, DEPT ENGN QUIM, INST SUPER TECN, P-1096 LISBON, PORTUGAL

来源：

COORDINATION CHEMISTRY REVIEWS | 1994年 / 135卷

关键词：

D O I：

10.1016/0010-8545(94)80082-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermochemical data for transition metal complexes containing phosphorus(III) ligands have been reviewed and used to derive and discuss metal-phosphine and metal-phosphite bond dissociation enthalpies. The survey is preceded by brief overviews of the nature of the M-P bond and of the steric and electronic properties of the phosphorus ligands. Also included is a critical survey of thermochemical data of phosphines and phosphites.

引用

页码：737 / 807

页数：71

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