THE CRYSTAL-CHEMISTRY AND DIELECTRIC-PROPERTIES OF THE AURIVILLIUS FAMILY OF COMPLEX BISMUTH OXIDES WITH PEROVSKITE-LIKE LAYERED STRUCTURES

被引：225

作者：

FRIT, B

MERCURIO, JP

机构：

[1] Laboratoire de Céramiques Nouvelles, U.R.A.-C.N.R.S. No. 320, Faculté des Sciences, 87060 Limoges Cedex, 123, Avenue A. Thomas

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1992年 / 188卷 / 1-2期

关键词：

D O I：

10.1016/0925-8388(92)90639-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Many Aurivillius phases of ferroelectric complex bismuth oxides are currently known. With the formula Bi2Am-1BmO3m+3, they all consist of Bi2O2 layers interleaved with perovskite-like Am-1BmO3m+1 layers. Their crystal chemistry and their chemical stability in relation to the number, m, of octahedral sheets within the perovskite-like layers and to various cationic substitutions, have been analysed. The possibility of their ordered intergrowth, i.e. the formation of the homologous series Bi4A2n-1B2n+1O6n+9 of mixed-layer structures has been examined and a comprehensive review of their dielectric properties with respect to various chemical substitutions and to different formation processes has been achieved, permitting an outline of their future potential applications.

引用

页码：27 / 35

页数：9

共 44 条

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