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RADICAL ANNULATION REACTIONS OF ALLYL IODOMALONONITRILES

被引：60
作者：
CURRAN, DP
SEONG, CM
机构：
[1] Department of Chemistry, University of Pittsburgh, Pittsburgh
来源：
TETRAHEDRON | 1992年 / 48卷 / 11期
关键词：
IODINE ATOM TRANSFER; RADICAL ANNULATION; NITRILE TRANSFER; IODOMALONONITRILE;
D O I：
10.1016/S0040-4020(01)88882-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Heating of allyl iodomalononitriles with alkenes, followed by tin hydride reduction, forms 1-(cyanalkyl)-4-cyanocyclopentane rings with up to 5 new stereocenters by a sequence of atom transfer addition followed by nitrile transfer cyclization.
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页码：2175 / 2190
页数：16
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