RADICAL ANNULATION REACTIONS OF ALLYL IODOMALONONITRILES

被引：60

作者：

CURRAN, DP

SEONG, CM

机构：

[1] Department of Chemistry, University of Pittsburgh, Pittsburgh

来源：

TETRAHEDRON | 1992年 / 48卷 / 11期

关键词：

IODINE ATOM TRANSFER; RADICAL ANNULATION; NITRILE TRANSFER; IODOMALONONITRILE;

D O I：

10.1016/S0040-4020(01)88882-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Heating of allyl iodomalononitriles with alkenes, followed by tin hydride reduction, forms 1-(cyanalkyl)-4-cyanocyclopentane rings with up to 5 new stereocenters by a sequence of atom transfer addition followed by nitrile transfer cyclization.

引用

页码：2175 / 2190

页数：16

共 47 条

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