2,2-DIFLUORO ENOL SILYL ETHERS - CONVENIENT PREPARATION AND APPLICATION TO THE SYNTHESIS OF A NOVEL FLUORINATED BRASSINOSTEROID

被引：52

作者：

JIN, FQ ^{[1
]}

XU, YY ^{[1
]}

HUANG, WY ^{[1
]}

机构：

[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 07期

关键词：

D O I：

10.1039/p19930000795

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

on treatment with Grignard reagents, trifluoroacetyltriphenylsilane was converted into 2,2-difluoro enol silyl ethers in almost quantitative yields. As a synthetic application of the 2,2-difluoro enol silyl ether, a novel fluorinated brassinosteroid was synthesized.

引用

页码：795 / 799

页数：5

共 29 条

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