SELF-ASSEMBLY OF A NEW CLASS OF TETRANUCLEAR COPPER(I) AND SILVER(I) COMPLEXES

被引：30

作者：

ZIESSEL, R ^{[1
]}

YOUINOU, MT ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST LE BEL,CHIM METAUX TRANSIT & CATALYSE LAB,CNRS,URA 424,F-67070 STRASBOURG,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 06期

关键词：

D O I：

10.1002/anie.199308771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two bipyridine units in the macrocycle and two phenanthroline arms are the noteworthy features of the new ligand 1, which reacts spontaneously with Cu(I) and Ag(I) ions to form tetranuclear, double-stranded helicates. In the copper complex the Cu ions, which have distorted tetrahedral coordination, lie at the corners of a regular rhombus.

引用

页码：877 / 880

页数：4

共 20 条

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