METAL CENTERS LINKED BY BIS(IMIDO)PHENYLENE LIGANDS - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF 1,3-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)] AND 1,4-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)]

被引:15
作者
HOGARTH, G
MALLORS, RL
NORMAN, T
机构
关键词
D O I
10.1039/c39930001721
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Addition of 2 equiv. of [WCl2(Ph2PMO)4] to 1,3- or 1,4-phenylenediisocyanate results in rapid oxidative addition of isocyanate affording the bis(imido)phenylene bridged tungsten(iv) complexes 1,3- and 1,4-[{cis,trans-WCl2(Ph2PMe)2(CO))2(mu-NC6H4N)], respectively; both have been characterised by X-ray crystallography.
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页码:1721 / 1723
页数:3
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