X-RAY CRYSTAL-STRUCTURE OF [(WCL3(PME2PH)2)2 (MU-NC6H4N-1,4)] - THE 1ST STRUCTURAL CHARACTERIZATION OF A BINUCLEAR COMPLEX CONTAINING A 1,4-PHENYLENEDIIMIDO BRIDGE

被引：22

作者：

CLEGG, W ^{[1
]}

ERRINGTON, RJ ^{[1
]}

HOCKLESS, DCR ^{[1
]}

KIRK, JM ^{[1
]}

REDSHAW, C ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

POLYHEDRON | 1992年 / 11卷 / 03期

关键词：

D O I：

10.1016/S0277-5387(00)83186-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [{WCl4}2{mu-NC6H4N-1,4}] (obtained from WOCl4 and C6H4 (NCO)2-1,4) with PMe2Ph results in the formation of reduced phosphine derivatives. Crystals of the tungsten(V) binuclear complex [{WCl3(PMe2Ph)2}2{mu-NC6H4N-1,4}] have been obtained and a single-crystal X-ray structural analysis shows the two mer, trans-WCl3 (PMe2Ph)2 fragments to be linked in an eclipsed conformation by a linear, pi-bonded 1,4-phenylenediimido bridge.

引用

页码：381 / 384

页数：4

共 14 条

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