THE FIRST [4+3] ANNULATION OF FISCHER CARBENE COMPLEXES WITH AZADIENES - FACILE SYNTHESIS OF AZEPINES

被引：30

作者：

BARLUENGA, J

TOMAS, M

BALLESTEROS, A

SANTAMARIA, J

LOPEZORTIZ, F

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 03期

关键词：

D O I：

10.1039/c39940000321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 3-iminoprop-1-enylamines 1 with pentacarbonyl(1-methoxyprop-2-enylidene)chromium(O) complexes leads stereoselectively to substituted 5H-6,7-dihydroazepines in high yields; the process takes place at low temperature and is thought to involve a tandem imine cyclopropanation-Cope rearrangement.

引用

页码：321 / 322

页数：2

共 12 条

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