COMPLEX FORMATION BY N-SUBSTITUTED ACETOACETAMIDES .4. ENTHALPIES AND ENTROPIES OF PROTONATION AND CHELATION OF ACETOACETANILIDE ANION

被引：21

作者：

HARRIES, HJ

WRIGHT, G

机构：

[1] Department of Chemistry, Derby and District College of Technology, Derby, England

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 10期

关键词：

D O I：

10.1016/0022-1902(69)80098-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The acid dissociation constant of acetoacetanilide and the stability constants of its Be(II) chelate have been determined over the range 10-40°C. From these results have been calculated ΔH° and ΔS° for the protonation and Be(II) chelation reactions of the acetoacetanilide anion. These results are discussed in relation to thermodynamic data available for other chelate systems. © 1969.

引用

页码：3149 / &

共 13 条

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