INTERNAL ROTATION IN PHENYLSILANE AND PHENYLGERMANE AND THEIR -D3 DERIVATIVES

被引：25

作者：

FLEMING, JW

BANWELL, CN

机构：

[1] The Chemical Laboratory, The University, Brighton, Sussex England

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1969年 / 31卷 / 02期

关键词：

D O I：

10.1016/0022-2852(69)90362-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Theory is presented by which the effects of free, or slightly hindered, internal rotation on the infrared spectra of a certain class of molecules may be considered. As examples, calculations based on the theory are compared with observations on the XY3 group vibrations of phenylsilane, phenylgermane, and their -D3 derivatives. Some estimates are given for the heights of the barriers hindering the motion in these molecules. © 1969.

引用

页码：318 / &

共 8 条

[1] DIMETHYLACETYLENE - AN ANALYSIS OF THEORY REQUIRED TO INTERPRET ITS VIBRATIONAL SPECTRUM
BUNKER, PR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (02) : 718 - &
[2] The normal vibrations of molecules with internal torsional motions
Crawford, BL
Wilson, EB
[J]. JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (04) : 323 - 329
[3] INTERNAL ROTATION IN PHENYLSILANE AND PHENYLGERMANE AND THEIR -D3 DERIVATIVES
FLEMING, JW
BANWELL, CN
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1969, 31 (02) : 318 - &
[4] INTERACTIONS BETWEEN ORDINARY VIBRATIONS + HINDERED INTERNAL ROTATION .2. THEORY OF INTERNAL ROTATION FINE STRUCTURE IN SOME PERPENDICULAR BANDS OF ETHANE-TYPE MOLECULES
KIRTMAN, B
[J]. JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (03) : 775 - &
[5] INTERACTIONS BETWEEN ORDINARY VIBRATIONS AND HINDERED INTERNAL ROTATION .1. ROTATIONAL ENERGIES
KIRTMAN, B
[J]. JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (11) : 2516 - &
[6] VIBRATION-ROTATION INTERACTION IN POLYATOMIC MOLECULES .1. ZETA-MATRICES
MEAL, JH
POLO, SR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1956, 24 (06) : 1119 - 1125
[7] VIBRATION-ROTATION INTERACTION IN POLYATOMIC MOLECULES .2. DETERMINATION OF CORIOLIS COUPLING COEFFICIENTS
MEAL, JH
POLO, SR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1956, 24 (06) : 1126 - 1133
[8] CALCULATION OF ENERGY LEVELS FOR INTERNAL TORSION AND OVER-ALL ROTATION .1. CH3BF2 TYPE MOLECULES
WILSON, EB
LIN, CC
LIDE, DR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1955, 23 (01) : 136 - 142

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