NEW COMPOUNDS K2-XV8016, TL2-XV8016 WITH HOLLANDITE TYPE STRUCTURE

被引:50
作者
ABRIEL, W
RAU, F
RANGE, KJ
机构
[1] Institut für Chemie der Universität Regensburg, D-8400 Regensburg
关键词
D O I
10.1016/0025-5408(79)90090-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
K2V8O16, K1.8V8O16 and Tl1.74V8O16 were synthesized by high pressure- high temperature treatment of KVO3 and TlVO3 in a modified Belt-type apparatus. The compounds crystallize tetragonal, space group I4/m. They are the first well-characterized Vanadium-hollandites and show a remarkable high occupation of the tunnel sites with univalent cations. © 1979.
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页码:1463 / 1468
页数:6
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