ORGANOSILVER COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURE OF THE YLIDE DISILVER COMPLEX [AGCH2P(S)PH2]2

被引：31

作者：

WANG, SN

FACKLER, JP

CARLSON, TF

机构：

[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLLEGE STN,TX 77843

[2] TEXAS A&M UNIV SYST,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 06期

关键词：

D O I：

10.1021/om00156a045

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Summary: A dimeric silver(I) complex, [Ag(CH2PPh2S)]2(1), was obtained by the reaction of Li(CH2PPh2S) with AgNO3 in THF solution at -78 °C. The X-ray crystal structure of 1 shows that the ylide ligand CH2PPh2S bridges two Ag1 atoms with a Ag’-Ag1 separation of 2.990 (2) A. 1 has a one-dimensional chain structure in the solid with an intermolecular Ag-Ag separation of 3.227 (2) Λ. © 1990, American Chemical Society. All rights reserved.

引用

页码：1973 / 1975

页数：3

共 25 条

[1] EXPERIMENTAL AND THEORETICAL-STUDIES OF DINUCLEAR GOLD(I) AND GOLD(II) PHOSPHORUS YLIDE COMPLEXES - OXIDATIVE ADDITION, HALIDE EXCHANGE, AND STRUCTURAL-PROPERTIES INCLUDING THE CRYSTAL AND MOLECULAR-STRUCTURES OF [AU(CH2)2PPH2]2 AND [AU(CH2)2PPH2]2(CH3)BRI
BASIL, JD
MURRAY, HH
FACKLER, JP
TOCHER, J
MAZANY, AM
TRZCINSKABANCROFT, B
KNACHEL, H
DUDIS, D
DELORD, TJ
MARLER, DO
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (24) : 6908 - 6915
[2] BECK J, 1986, Z NATURFORSCH B, V41, P4
[3] BECKER ED, 1980, HIGH RESOLUTION NMR
[4] Brevard C., 1981, HDB HIGH RESOLUTION
[5] EXPERIMENTAL AND THEORETICAL-STUDIES OF THE COPPER(I) AND SILVER(I) DINUCLEAR N,N'-DI-P-TOLYLFORMAMIDINATO COMPLEXES
COTTON, FA
FENG, XJ
MATUSZ, M
POLI, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (21) : 7077 - 7083
[6] SINGLE-CRYSTAL STUDY OF F-19 SHIELDING TENSORS OF A TRIFLUOROMETHYL GROUP
GRIFFIN, RG
BULLITT, JG
ELLETT, JD
WAUGH, JS
MEHRING, M
[J]. JOURNAL OF CHEMICAL PHYSICS, 1972, 57 (05) : 2147 - &
[7] Harris R. K., 1978, NMR PERIODIC TABLE
[8] Jones P.G., 1981, GOLD BULL, V14, P102
[9] LUMINESCENCE AND METAL-METAL INTERACTIONS IN BINUCLEAR GOLD(I) COMPOUNDS
KING, C
WANG, JC
KHAN, MNI
FACKLER, JP
[J]. INORGANIC CHEMISTRY, 1989, 28 (11) : 2145 - 2149
[10] ISOMERIC SPECIES OF [AUCH2P(S)(C6H5)2I]2 - MIXED-VALENT AU(I)-AU(III) AND ISOVALENT AU(II)-AU(II) COMPLEXES WITH THE SAME METHYLENETHIOPHOSPHINATE LIGAND
MAZANY, AM
FACKLER, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (03) : 801 - 802

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