ORGANOSILVER COMPLEXES - SYNTHESIS AND CRYSTAL-STRUCTURE OF THE YLIDE DISILVER COMPLEX [AGCH2P(S)PH2]2

被引：31

作者：

WANG, SN

FACKLER, JP

CARLSON, TF

机构：

[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLLEGE STN,TX 77843

[2] TEXAS A&M UNIV SYST,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 06期

关键词：

D O I：

10.1021/om00156a045

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Summary: A dimeric silver(I) complex, [Ag(CH2PPh2S)]2(1), was obtained by the reaction of Li(CH2PPh2S) with AgNO3 in THF solution at -78 °C. The X-ray crystal structure of 1 shows that the ylide ligand CH2PPh2S bridges two Ag1 atoms with a Ag’-Ag1 separation of 2.990 (2) A. 1 has a one-dimensional chain structure in the solid with an intermolecular Ag-Ag separation of 3.227 (2) Λ. © 1990, American Chemical Society. All rights reserved.

引用

页码：1973 / 1975

页数：3

共 25 条

[11] STRUCTURAL CHARACTERIZATION OF A LINEAR [AU=PT=AU] COMPLEX, AU2PT(CH2P(S)PH2)4, AND ITS OXIDIZED LINEAR METAL-METAL BONDED [AU-PT-AU] PRODUCT, AU2PT(CH2P(S)PH2)4CL2
MURRAY, HH
BRIGGS, DA
GARZON, G
RAPTIS, RG
PORTER, LC
FACKLER, JP
[J]. ORGANOMETALLICS, 1987, 6 (09) : 1992 - 1995
[12] SYNTHESES AND CRYSTAL-STRUCTURES OF COMPLEXES [M2R2] [M = CU, AG, OR AU, R = 2-C(SIME3)2C5H4N] AND [CU42-CH(SIME3)C5H4N] - ELECTROCHEMICAL GENERATION OF [CU2R2]2+
PAPASERGIO, RI
RASTON, CL
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (12): : 3085 - 3091
[13] Pauling L., 1960, LINUS PAULING NATURE, V3rd, P111
[14] A DINUCLEAR GOLD(II) YLIDE COMPLEX POSSESSING CHLORIDE LIGANDS AND BRIDGING METHYLENETHIOPHOSPHINATE GROUPS
PORTER, LC
FACKLER, JP
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 587 - 589
[15] METALLVERBINDUNGEN YLIDEN .7. STABLE COPPER AND SILVER DERIVATIVES OF PHOSPHORUS YLIDES
SCHMIDBAUR, H
ADLKOFER, J
HEIMANN, M
[J]. CHEMISCHE BERICHTE-RECUEIL, 1974, 107 (11): : 3697 - 3705
[16] NEW, UNUSUALLY STABLE TYPE OF ORGANO-COPPER AND ORGANO-SILVER COMPOUNDS
SCHMIDBAUR, H
ADLKOFER, J
BUCHNER, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1973, 12 (05) : 415 - 416
[17] PHOSPHORUS YLIDES IN THE COORDINATION SPHERE OF TRANSITION-METALS - AN INVENTORY
SCHMIDBAUR, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (12): : 907 - 927
[18] Schmidbaur H., 1980, GMELIN HDB ANORGANIS
[19] THE REACTION OF TRIPHENYLPHOSPHINE SULFIDE WITH ALKYLLITHIUM REAGENTS
SEYFERTH, D
WELCH, DE
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1964, 2 (01) : 1 - 7
[20] A NEW AND CONVENIENT ROUTE TO ORGANOFUNCTIONAL PHOSPHINE OXIDES AND SULFIDES
SEYFERTH, D
HEEREN, JK
WELCH, DE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (05) : 642 - &

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