SYNTHESIS OF BETA-LACTONES BY THE PHOTOCHEMICAL-REACTIONS OF CHROMIUM ALKOXYCARBENE COMPLEXES WITH ALDEHYDES

被引：22

作者：

COLSON, PJ ^{[1
]}

HEGEDUS, LS ^{[1
]}

机构：

[1] COLORADO STATE UNIV, DEPT CHEM, FT COLLINS, CO 80523 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 17期

关键词：

D O I：

10.1021/jo00096a047

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photolysis of chromium alkoxycarbene complexes with aldehydes in the presence of Lewis acids produced beta-lactones in low yield. Incorporation of the aldehyde into either side chain of the carbene complex resulted in intramolecular processes which were considerably more efficient.

引用

页码：4972 / 4976

页数：5

共 35 条

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