MELT RHEOLOGY OF HIGH-DENSITY POLYETHYLENE POLYAMIDE-6 BLENDS

被引:109
作者
UTRACKI, LA
DUMOULIN, MM
TOMA, P
机构
[1] Natl Research Council Canada,, Industrial Materials Research Inst,, Boucherville, Que, Can, Natl Research Council Canada, Industrial Materials Research Inst, Boucherville, Que, Can
关键词
MICROSCOPIC EXAMINATION - NYLON POLYMERS - PLASTICS - Morphology - POLYAMIDES - Blending;
D O I
10.1002/pen.760260108
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Commercial high density polyethylene and polyamide-6 (PA) resins were melt blended in the Brabender Plasticorder twin-screw extruder. The blends containing zero to 30 wt percent of polyamide-6 were examined in dynamic and steady state shear at 150, 200, and 250 degree C. The rheological test results are discussed in terms of morphology of the samples as observed under scanning electron microscope. Microscopy of the extrudates has shown a temperature dependent movement of the polyamide in the capillary during the extrusion and that fibrillation of the PA phase in the extensional field occurred at all temperatures.
引用
收藏
页码:34 / 44
页数:11
相关论文
共 52 条
[21]   PERMEABILITY OF OXYGEN AND WATER-VAPOR THROUGH POLYETHYLENE POLYAMIDE FILMS [J].
KAMAL, MR ;
JINNAH, IA ;
UTRACKI, LA .
POLYMER ENGINEERING AND SCIENCE, 1984, 24 (17) :1337-1347
[22]  
KAMAL MR, 1984, APR NRCC IMRI POL 84
[23]   POLYPROPYLENE NYLON-6 BLENDS - PHASE DISTRIBUTION MORPHOLOGY, RHEOLOGICAL MEASUREMENTS, AND STRUCTURE DEVELOPMENT IN MELT SPINNING [J].
LIANG, BR ;
WHITE, JL ;
SPRUIELL, JE ;
GOSWAMI, BC .
JOURNAL OF APPLIED POLYMER SCIENCE, 1983, 28 (06) :2011-2032
[25]  
MAGAT EE, 1967, Patent No. 3329557
[26]  
NIKOLAIEVA AP, 1982, KHIM TECHNOL, V3, P10
[27]  
Rabinowitsch B, 1929, Z PHYS CHEM A-CHEM T, V145, P1
[28]  
ROMANKIEVICH OV, 1984, KHIM VOLOK, V1, P21
[29]   N-ACETYLPOLYETHYLENIMINE - A BLENDING AGENT FOR POLYAMIDE FIBER [J].
SANO, Y ;
MIYAMOTO, M ;
KIMURA, Y ;
SAEGUSA, T .
POLYMER BULLETIN, 1981, 6 (3-4) :163-168
[30]   MOLECULAR FRACTIONATION IN CAPILLARY FLOW OF POLYMER FLUIDS [J].
SCHREIBER, HP ;
STOREY, SH .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1965, 3 (9PB) :723-+