SYNTHESIS OF 1,3-DIOXIN-4-ONES HAVING A TRIFLUOROMETHYL GROUP AT THE 5-POSITION - VERSATILE BUILDING-BLOCKS FOR TRIFLUOROMETHYLATED COMPOUNDS

被引：5

作者：

IWAOKA, T ^{[1
]}

SATO, M ^{[1
]}

KANEKO, C ^{[1
]}

机构：

[1] TOHOKU UNIV,INST PHARMACEUT,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 18期

关键词：

D O I：

10.1039/c39910001241

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 5-iodo-1,3-dioxin-4-ones with trifluoromethyl iodide in the presence of copper power in hexamethylphosphoric triamide affords the title compounds, which can be converted either to alpha-trifluoromethylated beta-keto acid derivatives or to uracil or oxazine derivatives bearing a trifluoromethyl group.

引用

页码：1241 / 1242

页数：2