2-DIMENSIONAL C-13,HG-199 CORRELATION - A NEW NMR METHOD FOR CHARACTERIZATION OF ORGANOMERCURY COMPOUNDS

被引:8
作者
FACKE, T [1 ]
BERGER, S [1 ]
机构
[1] UNIV MARBURG,DEPT CHEM,HANS MEERWEIN STR,D-35032 MARBURG,GERMANY
关键词
NUCLEAR MAGNETIC RESONANCE; MERCURY; CORRELATION SPECTROSCOPY;
D O I
10.1016/0022-328X(94)88102-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two-dimensional C-13, Hg-199 correlation has been used for the first time to facilitate assignments for C-13 and Hg-199 spins in a dimercury compound. Correlations over more than one bond provide additional information on the constitution of these molecules. Unusual C-13 isotope effects on the Hg-199 chemical shifts are reported.
引用
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页码:35 / 38
页数:4
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