NEW SYNTHETIC ROUTE TO POLYHEDRAL ORGANYLSILSESQUIOXANES

被引：47

作者：

HERREN, D ^{[1
]}

BURGY, H ^{[1
]}

CALZAFERRI, G ^{[1
]}

机构：

[1] UNIV BERN,INST INORGAN & PHYS CHEM,CH-3000 BERN 9,SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1991年 / 74卷 / 01期

关键词：

D O I：

10.1002/hlca.19910740105

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrosilation of methylenecyclohexane and hex-l-ene by octa(hydridosilsesquioxane) catalysed by hexachloroplatinic acid is a new route to polyhedral organylsilsesquioxanes. Quantitative yield of octa(cyclohexyl-methylsilsesquioxane) is reached. This reaction opens a vast field of yet unknown polyhedral silsesquioxanes.

引用

页码：24 / 26

页数：3

共 19 条

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