MOSSBAUER AND ESR STUDY OF THE FORMATION OF PHTHALOCYANINIRON (II) PYRIDINE ADDUCT IN THE SUPERCAGE OF NAY, KY, AND RBY ZEOLITE

被引：8

作者：

TANAKA, M ^{[1
]}

MINAI, Y ^{[1
]}

WATANABE, T ^{[1
]}

TOMINAGA, T ^{[1
]}

机构：

[1] TOKYO UNIV MARINE SCI,KONAN,TOKYO 108,JAPAN

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-LETTERS | 1992年 / 164卷 / 04期

关键词：

D O I：

10.1007/BF02165281

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Phthalocyanineiron(II) (FePc) and phthalocyaninato[(2-)bispyridine]iron(II) (FePc(py)2) synthesized in supercage of NaY, KY and RbY zeolite have been characterized by Mossbauer and ESR spectroscopy. The yield of formation of the pyridine adduct depends on the ionic radius of the alkali ions introduced into the supercage, but not on the number of iron ions trapped in the cages, suggesting that free space in the supercage was the most important factor for the formation of the FePc-py-adducts.

引用

页码：255 / 264

页数：10