THERMODYNAMICS OF AMMONIUM HALOPALLIDATES .1. HEAT-CAPACITY AND THERMODYNAMIC PROPERTIES OF (NH4)2PDCL6 AT TEMPERATURES FROM 6-K TO 350-K

被引：15

作者：

CALLANAN, JE

WEIR, RD

WESTRUM, EF

机构：

[1] ROYAL MIL COLL CANADA,DEPT CHEM & CHEM ENGN,KINGSTON K7K 5L0,ONTARIO,CANADA

[2] CALLANAN ASSOCIATES,BOULDER,CO 80301

[3] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1992年 / 24卷 / 09期

关键词：

D O I：

10.1016/S0021-9614(05)80010-2

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The heat capacity of ammonium hexachloropallidate (NH4)2PdCl6 was measured at temperatures from 6 K to 350 K by adiabatic calorimetry. The heat-capacity curve is smooth and without anomalies. It rises rapidly from T0 to T = 150 K where the Cp,m value is 26.62 · R (R = 8.31451 J · K-1 · mol-1). Above T = 150 K, the increase to 32.41 · R at 350 K occurs more slowly. Values of the standard thermodynamioc quantities are tabulated to T = 350 K. © 1992 Academic Press Limited All rights reserved.

引用

页码：1001 / 1007

页数：7