CONTROL OF CHEMICAL-DYNAMICS BY RESTRICTING INTRAMOLECULAR VIBRATIONAL-RELAXATION

被引:29
作者
GOSWAMI, D [1 ]
WARREN, WS [1 ]
机构
[1] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08544
关键词
D O I
10.1063/1.466050
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We address the issue of localization of bond energy in a molecule by stopping intramolecular vibrational relaxation (IVR). We show through model calculations that appropriate frequency sweeps permit selective locking over a well-defined range of resonance frequencies, with little excitation outside that range. We also propose a modified version of an adiabatic half passage experiment that will perform photon locking without complications from inhomogeneities or partial excitation of other transitions for a bright state coupled to a finite number of dark states.
引用
收藏
页码:4509 / 4517
页数:9
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