ELECTRONIC-PROPERTIES OF GOLD ON MO(110) - D-]S,P CHARGE REDISTRIBUTION AND VALENCE-BAND SHIFTS

被引：54

作者：

RODRIGUEZ, JA

KUHN, M

机构：

[1] Department of Chemistry, Brookhaven National Laboratory, Upton, NY 11973-5000

来源：

SURFACE SCIENCE | 1995年 / 330卷 / 01期

关键词：

AB-INITIO QUANTUM CHEMICAL METHODS AND CALCULATIONS; ATOM SOLID INTERACTIONS; GOLD; METAL-METAL INTERFACES; MOLYBDENUM; THERMAL DESORPTION SPECTROSCOPY; X-RAY PHOTOELECTRON SPECTROSCOPY;

D O I：

10.1016/0039-6028(95)00431-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interaction between Au atoms and Mo(110) has been investigated using photoelectron spectroscopy and ab initio self-consistent field calculations. The formation of Au-Mo bonds induces shifts toward higher binding energy (0.3-0.7 eV) in the core levels and valence d band of gold. This is accompanied by an important redistribution of charge, in which Au loses 5d electrons and gains (6s,6p) electrons. The positive binding-energy shifts in the Au 4f levels and 5d band reflect the effects of a Mo-induced reduction in the Au 5d electron population.

引用

页码：L657 / L664

页数：8

共 66 条

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