THERMOLYTIC REACTIONS OF BENZOTRIAZINONE AND ISATOIC ANHYDRIDE

被引:49
作者
CRABTREE, HE
SMALLEY, RK
SUSCHITZKY, H
机构
[1] Department of Pure and Applied Chemistry, University of Salford, Salford
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 22期
关键词
D O I
10.1039/j39680002730
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Benzotriazinone loses nitrogen on thermolysis in solution to give a heterodiene which reacts with dienophiles such as benzyne and p-methoxybenzaldehyde. Isatoic anhydride in hot solvents is attacked nucleophilically by esters with loss of carbon dioxide to give benzoxazinones.
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页码:2730 / +
页数:1
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