HYDROXIDE COMPLEXES OF LANTHANIDES .2. SAMARIUM(III) IN PERCHLORATE MEDIUM

被引：27

作者：

KRAGTEN, J ^{[1
]}

DECNOPWEEVER, LG ^{[1
]}

机构：

[1] UNIV AMSTERDAM,ANALYT CHEM LAB,NL-1018 WV AMSTERDAM,NETHERLANDS

来源：

TALANTA | 1979年 / 26卷 / 12期

关键词：

D O I：

10.1016/0039-9140(79)80025-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

From the precipitation borderline in the pM′-pH diagram, determined experimentally under CO2-free conditions, the stability constants of the mononuclear and polynuclear species of samarium hydroxide have been established. The values found are log*β1 = -7.5, log*β2 = -15.0, log*β3 = -22.7, logβ4, 3 = -19.5 and log*Ks0 = 17.5. They refer to fresh precipitates, prepared at room temperature in sodium perchlorate medium with an ionic strength of 1. © 1979.

引用

页码：1105 / 1109

页数：5

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