DIRECT ELECTROCHEMICAL SYNTHESIS OF PYRIMIDINE-2-THIONATO COMPLEXES OF ZINC(II) AND CADMIUM(II) - THE CRYSTAL-STRUCTURE OF (1,10-PHENANTHROLINE)BIS(PYRIMIDINE-2-THIONATO)CADMIUM(II)

被引：42

作者：

CASTRO, R

DURAN, ML

GARCIAVAZQUEZ, JA

ROMERO, J

SOUSA, A

CASTINEIRAS, A

HILLER, W

STRAHLE, J

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,SANTIAGO,SPAIN

[2] UNIV TUBINGEN,INST ANORGAN CHEM,W-7400 TUBINGEN 1,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1992年 / 47卷 / 08期

关键词：

X-RAY; CADMIUM COMPLEXES; PYRIMIDINE-2-THIONE; ZINC COMPLEXES;

D O I：

10.1515/znb-1992-0803

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zn(pymt)2 and Cd(pymt)2 complexes have been obtained by electrochemical oxidation of anodic zinc or cadmium in acetonitrile solutions or pyrimidine-2-thione (Hpymt). When 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen) was added to the electrochemical cell, the adducts [M(pymt)2(bipy)], or [M(pymt)2(phen)] (M = Zn or Cd) were obtained. Crystals of [Cd(pymt)2phen] are orthorhombic, with a = 9.882(2), b = 12.491(1), c = 16.513(2)angstrom, space group P2(1)2(1)2(1) and Z = 4. The cadmium atom has distorted octahedral geometry, and one nitrogen atom of each pyrimidine-2-thiolato ligand is not coordinated.

引用

页码：1067 / 1074

页数：8

共 52 条

[31] THE ANION OF PYRIMIDINE-2-THIOL AS A LIGAND TO MOLYBDENUM, TUNGSTEN, AND IRON - PREPARATION OF COMPLEXES, THEIR STRUCTURE AND REACTIVITY
LATHAM, IA
LEIGH, GJ
PICKETT, CJ
HUTTNER, G
JIBRILL, I
ZUBIETA, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (06): : 1181 - 1187
[32] COPPER(I) BROMIDE COMPLEXES WITH HETEROCYCLIC THIONES AND TRIPHENYLPHOSPHINE AS LIGANDS - THE X-RAY CRYSTAL-STRUCTURE OF COPPER(I) PYRIMIDINE-2-THIONE BIS (TRIPHENYLPHOSPHINE) BROMIDE [CU(PPH3)2(PYMTH)BR]
LECOMTE, C
SKOULIKA, S
ASLANIDIS, P
KARAGIANNIDIS, P
PAPASTEFANOU, S
[J]. POLYHEDRON, 1989, 8 (08) : 1103 - 1109
[33] THE DIRECT ELECTROCHEMICAL SYNTHESIS OF TIN(II) DERIVATIVES OF AROMATIC 1,2-DIOLS, AND A STUDY OF THEIR OXIDATIVE ADDITION-REACTIONS
MABROUK, HE
TUCK, DG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (10): : 2539 - 2543
[34] CRYSTAL AND MOLECULAR-STRUCTURE OF DICHLOROBIS(2-PYRIDINETHIOLATO)TIN(IV)
MASAKI, M
MATSUNAMI, S
UEDA, H
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (11) : 3298 - 3301
[35] ASPECTS OF THE INORGANIC-CHEMISTRY OF RUBBER VULCANIZATION .3. ANIONIC CADMIUM COMPLEXES DERIVED FROM DIALKYLDITHIOCARBAMATES, 2-MERCAPTOBENZOTHIAZOLE AND ITS DERIVATIVES, AND DIALKYL DITHIOPHOSPHATES, AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF [NBUN4][CD(S2CNET2)3], [NET4][CD(C7H4NS2)3], AND [NME4][CD(S2P(OPRI)2)3ZO
MCCLEVERTY, JA
GILL, S
KOWALSKI, RSZ
BAILEY, NA
ADAMS, H
LUMBARD, KW
MURPHY, MA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (03): : 493 - 503
[36] COMPLEXES OF THE PLATINUM METALS .29. PYRIDINE-2-THIOLATE DERIVATIVES OF RUTHENIUM AND OSMIUM - X-RAY CRYSTAL-STRUCTURES OF [RU(C5H4NS)2(CO)2(PPH3)] AND [RU(C5H4NS)2(CO)(PPH3)]
MURA, P
OLBY, BG
ROBINSON, SD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (10): : 2101 - 2112
[37] DISPLACEMENT OF COORDINATED CARBON-MONOXIDE AS A RESULT OF AN INTRAMOLECULAR NUCLEOPHILIC-ATTACK - CRYSTAL AND MOLECULAR-STRUCTURE OF THE INTERMEDIATE, CIS-DICARBONYL BIS(PYRIDINE-2-THIOLATO)TRIPHENYLPHOSPHINERUTHENIUM(II), AND OF THE PRODUCT, MONOCARBONYL BIS(PYRIDINE-2-THIOLATO)TRIPHENYLPHOSPHINE RUTHENIUM(II)
MURA, P
OLBY, BG
ROBINSON, SD
[J]. INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 98 (02): : L21 - L22
[38] CRYSTAL STRUCTURE OF CADMIUM CHLORIDE BISPYRIDINE
PAULUS, H
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1969, 369 (1-2): : 38 - &
[39] CRYSTAL-STRUCTURE OF BIS(O-ETHYLXANTHATO)-1,10-PHENANTHROLINECADMIUM(2)
RASTON, CL
WHITE, AH
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1976, 29 (04) : 739 - 742
[40] CONVENIENT SYNTHESIS, PROPERTIES AND THE STRUCTURE OF TETRAMETHYLAMMONIUM TRIS(PYRIMIDINE-2-THIOLATO)FERRATE(II) - AN IRON COMPLEX WITH 3 STABLE 4-MEMBERED N,S-CHELATE RINGS
ROSENFIELD, SG
MASCHARAK, PK
ARORA, SK
[J]. INORGANICA CHIMICA ACTA, 1987, 129 (01) : 39 - 46

← 1 2 3 4 5 6 →