REACTIONS OF (1-CHLOROVINYL)DIPHENYLPHOSPHINE OXIDE WITH ORGANOMETALLIC REAGENTS

被引：12

作者：

CARDELLICCHIO, C

FIANDANESE, V

NASO, F

PIETRUSIEWICZ, KM

WISNIEWSKI, W

机构：

[1] CNR,DIPARTIMENTO CHIM,CTR STUDIO METODOL INNOVAT SINTESI ORGANICHE,I-70126 BARI,ITALY

[2] POLISH ACAD SCI,CTR MOLEC & MACROMOLEC STUDIES,PL-90363 LODZ,POLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(00)93399-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct substitution of 1-chlorovinyl group by an aryl or an alkyl group in the reactions of (1-chlorovinyl)diphenylphosphine oxide with aryl and alkyl Grignard reagents was observed, whereas in its reactions with the corresponding cuprates addition across the double bond constituted the dominant reaction pathway.

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收藏

页码：3135 / 3138

页数：4

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