SURFACTANTS .13. SYNTHESES OF SODIUM 2-ACYLAMINO-2,6-DIDEOXY-D-GLUCOPYRANOSE-6-SULPHONATES

被引：18

作者：

FERNANDEZBOLANOS, J ^{[1
]}

CASTILLA, IM ^{[1
]}

GUZMAN, JF ^{[1
]}

机构：

[1] CSIC, INST GRASA & DERIVADOS, SEVILLE, SPAIN

来源：

CARBOHYDRATE RESEARCH | 1988年 / 173卷 / 01期

关键词：

D O I：

10.1016/S0008-6215(00)90800-0

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Sodium 2-acylamino(otanamido, dodecanamido, hexadecanamido)-2,6-di-deoxy-D-glucopyranose-6-sulphonates (14-16) were synthesised by N-acylation of 2-amino-2,6-dideoxy-D-glucopyranose-6-sulphonic acid. Compound 14 was also obtained by oxidation of 1,3,4-tri-O-acetyl-6-S-acetyl-2-deoxy-2-octanamido-6-thio-.alpha.-D-glucopyranose with hydrogen peroxide followed by deacetylation, and 15 by oxidation of 6,6''-dithiobis(2,6-dideoxy-2-dodecanamido-D-glucopyranose) with hydrogen peroxide.

引用

页码：33 / 40

页数：8

共 24 条

[11] SYNTHESIS OF 3-O-(6-DEOXY-6-SULPHO-ALPHA-D-GLUCOPYRANOSYL)-1,2-DI-O-HEXADECANOYL-L-GLYCEROL, SULPHOQUINOVOSYL DIGLYCERIDE [J].