BRANCHED LONG-CHAIN ALKYL METHYL ETHERS - A NEW CLASS OF LIPIDS FROM SPIDER SILK

被引：26

作者：

SCHULZ, S ^{[1
]}

TOFT, S ^{[1
]}

机构：

[1] BIOL INST, AFDELING ZOOL, DK-8000 AARHUS C, DENMARK

来源：

TETRAHEDRON | 1993年 / 49卷 / 31期

关键词：

D O I：

10.1016/S0040-4020(01)80424-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Long chain methyl branched 1-methoxyalkanes, a new class of ether lipids, have been identified from silk of the spider Linyphia triangularis (Araneae: Linyphiidae) by use of gas chromatographic retention indices, GC/MS investigations, and chemical modifications. Methyl groups are predominantly located at C-2, and omega-3 or omega-2 positions, respectively. Chain length varies between C24 and C32. The synthesis of representative compounds is reported.

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页码：6805 / 6820

页数：16

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