ISOTACTIC POLYMETHOXY-1-ALKENES FROM THE TERRESTRIAL BLUE-GREEN-ALGA SCYTONEMA-OCELLATUM - STRUCTURE AND SYNTHESIS

被引：15

作者：

MORI, Y ^{[1
]}

KOHCHI, Y ^{[1
]}

NOGUCHI, H ^{[1
]}

SUZUKI, M ^{[1
]}

CARMELI, S ^{[1
]}

MOORE, RE ^{[1
]}

PATTERSON, GML ^{[1
]}

机构：

[1] UNIV HAWAII,DEPT CHEM,HONOLULU,HI 96822

来源：

TETRAHEDRON | 1991年 / 47卷 / 27期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4020(01)80955-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel isotactic polymethoxy-1-alkenes 2-5 were isolated from the tolytoxin-producing blue-green alga Scytonema ocellatum. The gross structures and relative configurations were determined by NMR and mass spectral analysis. Synthesis of optically active 2-4 in a stereocontrolled manner established their absolute configurations.

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页码：4889 / 4904

页数：16

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