DIENYL COMPLEXES OF TRANSITION METALS .3. ADDITION OF HYDRIDE TO METHOXY-SUBSTITUTED ARENECYCLOPENTADIENYLIRON CATIONS

被引：52

作者：

KHAND, IU

PAUSON, PL

WATTS, WE

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 01期

关键词：

D O I：

10.1039/j39690000116

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of hydride to a series of (methoxyarene)cyclopentadienyliron cations has been shown to occur exclusively at the arene ring, to give the corresponding (methoxycyclohexadienyl)cyclopentadienyliron complexes. With respect to the methoxy-substituent, site reactivity decreases in the order meta > para > ortho. Partial demethoxylation occurred during these reactions.

引用

页码：116 / &

共 4 条

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KHAND, IU ;

PAUSON, PL ;

WATTS, WE .

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[2]

KHAND IU, 1968, J CHEM SOC C, P2261, DOI 10.1039/j39680002261

[3] FERROCENE DERIVATIVES .19. SUBSTITUTION PATTERNS [J].

KNOX, GR ;

MORRISON, IG ;

PAUSON, PL ;

SANDHU, MA ;

WATTS, WE .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (19) :1853-+

[4]

NESMEYAN.AN, 1966, DOKL AKAD NAUK SSSR+, V166, P607

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