IMINE-TRANSFER REACTIONS FROM ZIRCONIUM TO PHOSPHORUS AND BORON - SYNTHESIS OF THE 1ST C-PHOSPHANYL-BORANYL, N-PHOSPHANYL-BORANYL, OR N-BORANYLIMINES

被引:21
作者
BOUTONNET, F [1 ]
DUFOUR, N [1 ]
STRAW, T [1 ]
IGAU, A [1 ]
MAJORAL, JP [1 ]
机构
[1] CNRS, CHIM COORDINAT LAB, 205 ROUTE NARBONNE, F-31077 TOULOUSE, FRANCE
关键词
D O I
10.1021/om00057a028
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A "one-pot" reaction involving (i-Pr2N)2PCN (1), the Schwartz reagent Cp2ZrHCl (2), and halogenated phosphorus or boron species allows the synthesis of the first C-phosphanyl-, N-phosphanyl-, or N-boranylimines, 4-8.
引用
收藏
页码:3939 / 3941
页数:3
相关论文
共 18 条
[1]   REACTIONS OF ALKYL AND HYDRIDE DERIVATIVES OF PERMETHYLSCANDOCENE AND PERMETHYLZIRCONOCENE WITH NITRILES AND AMINES - CATALYTIC-HYDROGENATION OF TERT-BUTYL CYANIDE WITH PERMETHYLSCANDOCENE HYDRIDE [J].
BERCAW, JE ;
DAVIES, DL ;
WOLCZANSKI, PT .
ORGANOMETALLICS, 1986, 5 (03) :443-450
[2]  
BRODIE NMJ, UNPUB
[3]   THE SYNTHESIS AND STRUCTURE OF STIBAINDOLES [J].
BUCHWALD, SL ;
FISHER, RA ;
FOXMAN, BM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (07) :771-772
[4]   A MODIFIED PROCEDURE FOR THE PREPARATION OF CP2ZR(H)CL (SCHWARTZ REAGENT) [J].
BUCHWALD, SL ;
LAMAIRE, SJ ;
NIELSEN, RB ;
WATSON, BT ;
KING, SM .
TETRAHEDRON LETTERS, 1987, 28 (34) :3895-3898
[5]   X-RAY STRUCTURE-ANALYSIS AND REACTIVITY OF THE ZIRCONAAZAPHOSPHIRANE CP2ZR(CL)N(SIME3)P(H)N(SIME3)2 [J].
DUFOUR, N ;
MAJORAL, JP ;
CAMINADE, AM ;
CHOUKROUN, R ;
DROMZEE, Y .
ORGANOMETALLICS, 1991, 10 (01) :45-48
[6]   SYNTHESIS OF MAIN GROUP HETEROCYCLES BY METALLACYCLE TRANSFER FROM ZIRCONIUM [J].
FAGAN, PJ ;
NUGENT, WA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (07) :2310-2312
[7]   STIBATHIOLANES - SYNTHESIS, SOLID-STATE STRUCTURE, AND SOLUTION BEHAVIOR [J].
FISHER, RA ;
NIELSEN, RB ;
DAVIS, WM ;
BUCHWALD, SL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) :165-171
[8]   HYDROZIRCONATION OF NITRILES - THE FORMATION OF MONONUCLEAR AND BINUCLEAR (ALKYLIDENE-AMIDO)ZIRCONOCENE COMPLEXES [J].
FROMBERG, W ;
ERKER, G .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 280 (03) :343-354
[9]   TRANSITION-METAL DIENYLS IN ORGANIC-SYNTHESIS - DIENYL TRANSFER-REACTIONS FROM ZIRCONIUM TO PHOSPHORUS AND TO BORON [J].
FRYZUK, MD ;
BATES, GS ;
STONE, C .
JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (18) :4425-4426
[10]   TRANSITION-METAL DIENYLS IN ORGANIC-SYNTHESIS - A CONVENIENT PREPARATION OF SIGMA-BONDED TIN AND ZIRCONIUM DIENYLS [J].
FRYZUK, MD ;
BATES, GS ;
STONE, C .
TETRAHEDRON LETTERS, 1986, 27 (14) :1537-1540