FORMATION AND DESORPTION OF ALUMINUM-HYDRIDE FROM HYDROGEN ADSORBED ALUMINUM SURFACES

被引：43

作者：

HARA, M

DOMEN, K

ONISHI, T

NOZOYE, H

NISHIHARA, C

KAISE, Y

SHINDO, H

机构：

[1] NATL CHEM LAB IND,1-1 HIGASHI,TSUKUBA,IBARAKI 305,JAPAN

[2] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

SURFACE SCIENCE | 1991年 / 242卷 / 1-3期

关键词：

D O I：

10.1016/0039-6028(91)90309-G

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogen adsorbed Al single crystal surfaces have been investigated under ultra-high vacuum by thermal desorption (TD) and X-ray photoelectron spectroscopy (XPS). The desorption of an aluminum hydride at 340 K was observed to be zero-order by TD experiments of an Al(111) surface on which hydrogen adsorbed at 150 K. This is a first observation of the desorption of a metal from a hydrogen adsorbed metal surface. XP spectra of Al2p for hydrogen adsorbed Al film on Mo(111) indicated that the precursor of the desorbed aluminum hydride, which desorbed as zero-order, was formed with an increase of the temperature of the Al film up to 340 K.

引用

页码：459 / 463

页数：5

共 12 条

[1]

[Anonymous], 1962, VACUUM

[2]

Breisacher P, 1964, J AM CHEM SOC, V86, P5053

[3]

BRUCE LA, 1978, PHILOS MAG A, V38, P223

[4]

HARA M, IN PRESS

[5] SURFACE PHASES OF NI(110) INDUCED BY ADSORPTION OF DEUTERIUM [J].

JACKMAN, TE ;

GRIFFITHS, K ;

UNERTL, WN ;

DAVIES, JA ;

GURTLER, KH ;

HARRINGTON, DA ;

NORTON, PR .

SURFACE SCIENCE, 1987, 179 (2-3) :297-321

[6]

KERN R, 1980, SURF SCI, V93, pL101, DOI 10.1016/0039-6028(80)90040-0

[7]

KNOR Z, 1982, CATALYSIS SCI TECHNO, V3

[8]

MANDENER JM, 1988, CHEM PHYS LETT, V143, P593

[9]

MENZEL D, 1975, TOPICS APPLIED PHYSI, V4

[10] THERMODYNAMIC PROPERTIES OF ALUMINUM HYDRIDE [J].

SINKE, GC ;

WALKER, LC ;

OETTING, FL ;

STULL, DR .

JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (08) :2759-&

← 1 2 →