FORMATION OF HETEROBICYCLIC COMPOUNDS THROUGH SUCCESSIVE INSERTION OF ISOCYANIDES INTO A PALLADIUM HYDRIDE BOND

被引：13

作者：

TANASE, T

OHIZUMI, T

KOBAYASHI, K

YAMAMOTO, Y

机构：

[1] TOHO UNIV,FAC SCI,DEPT CHEM,FUNABASHI,CHIBA 274,JAPAN

[2] INST PHYS & CHEM RES,WAKO,SAITAMA 351,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 09期

关键词：

D O I：

10.1039/c39920000707

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of PdCl2(PPh3)2 1 with an excess of H2SiMePh and 2,6-xylyl isocyanide gives Pd{C(= NR)C(= NR)C(= NR)C(= NR)CH(= NR)}(C = NR)Cl.1/2C6H6 (3, R = 2,6-xylyl) and heterobicyclic compound, 2,6-(2',6'-xylyl)2-3,7-(N-2',6'-xylylimino)2-4,8-(N-2',6'-xylylamino)2-2,6-diaza-bicyclo[3.3.0]octa-4,8-diene 4; the structures of which have been determined by X-ray analysis.

引用

页码：707 / 708

页数：2

共 18 条

[1] ISOCYANIDE INSERTION REACTIONS AND THEIR ROLE IN THE CLUSTER-CATALYZED HYDROGENATION OF ISOCYANIDE MOLECULES
ADAMS, RD
GOLEMBESKI, NM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (10) : 2579 - 2587
[2] INSERTION OF ISOCYANIDE INTO A PLATINUM-HYDRIDE BOND - SYNTHESIS OF NEW SECONDARY CARBENE COMPLEXES
CHRISTIAN, DF
CLARK, HC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 85 (01) : C9 - C12
[3] CLARK GR, 1975, J CHEM SOC DA, P2446
[4] CHEMISTRY OF ETA-2-ACYL, ETA-2-IMINOACYL, AND RELATED FUNCTIONAL-GROUPS
DURFEE, LD
ROTHWELL, IP
[J]. CHEMICAL REVIEWS, 1988, 88 (07) : 1059 - 1079
[5] ORGANOLANTHANIDE AND ORGANOYTTRIUM HYDRIDE CHEMISTRY .4. REACTION OF ISOCYANIDES WITH [(C5H4R)2YH(THF)]2 TO FORM A STRUCTURALLY CHARACTERIZED N-ALKYLFORMIMIDOYL COMPLEX
EVANS, WJ
MEADOWS, JH
HUNTER, WE
ATWOOD, JL
[J]. ORGANOMETALLICS, 1983, 2 (09) : 1252 - 1254
[6] KUDO K, 1970, J CHEM SOC CHEM COMM, P1701
[7] ISOCYANIDE INSERTION REACTIONS OF MANGANESE(I) ALKYL AND IMINOACYL COMPLEXES
MOTZ, PL
ALEXANDER, JJ
HO, DM
[J]. ORGANOMETALLICS, 1989, 8 (11) : 2589 - 2601
[8] SIGMA-ALKYL OR SIGMA-ACYL ISOCYANIDE COMPLEXES OF NICKEL(II) AND PALLADIUM(II) . PREPARATION AND SUCCESSIVE INSERTION REACTIONS
OTSUKA, S
NAKAMURA, A
YOSHIDA, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (25) : 7196 - &
[9] THE REACTIVITY OF THE UNSATURATED DIMERIC RHENIUM COMPLEXES [RE2H2(CO)6((ETO)2POP(OET)2)] AND [RE2H2(CO)6(PH2PCH2PPH2)] - X-RAY CRYSTAL-STRUCTURE OF [RE2H(CO)6(PH2PCH2PPH2)(MU-NC(H)ME)]
PREST, DW
MAYS, MJ
RAITHBY, PR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (10): : 2021 - 2028
[10] COBALT-CATALYZED PREPARATION OF DIIMINOFURAN DERIVATIVES THROUGH DOUBLE INSERTION OF ISOCYANIDE INTO A METAL-CARBON BOND
SUGANO, K
TANASE, T
KOBAYASHI, K
YAMAMOTO, Y
[J]. CHEMISTRY LETTERS, 1991, (06) : 921 - 924

← 1 2 →