PHOTOFRAGMENTATION VOLTAMMETRY STUDIES OF THE AMINOCARBENE COMPLEXES [(ETA(5)-C5H5)FE(CO)(L)(=C(NHR(1))(R(2))]BF4 [L = PPH3, P(P-TOL)3, R(1) = ME, CH2PH, R(2) = ME, BU]

被引：12

作者：

DAVIES, SG ^{[1
]}

METZLER, MR ^{[1
]}

WATKINS, WC ^{[1
]}

COMPTON, RG ^{[1
]}

BOOTH, J ^{[1
]}

EKLUND, JC ^{[1
]}

机构：

[1] PHYS CHEM LAB,OXFORD OX1 3QZ,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 09期

关键词：

D O I：

10.1039/p29930001603

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of the complexes [(eta5-C5H5)Fe(CO)(L){=C(NHR1)(R2)}]BF4 [L = PPh3, P(p-Tol)3; R1 = Me, CH2Ph; R2 = Me, Bu] is described. Photofragmentation voltammetry is used to demonstrate that the primary photoprocess is loss of the phosphine ligand in all four carbene complexes. A common intermediate is observed when the analogous aminocarbenes are studied.

引用

页码：1603 / 1609

页数：7

共 15 条

[1] BASE PROMOTED REARRANGEMENTS OF CYCLOPENTADIENYLACYL-METAL AND CYCLOPENTADIENYLCARBOXYALKYL-METAL COMPLEXES
ABBOTT, S
BAIRD, GJ
DAVIES, SG
DORDORHEDGECOCK, IM
MABERLY, TR
WALKER, JC
WARNER, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 289 (01) : C13 - C17
[2] Albeary W.J., 1975, ELECTRODE KINETICS
[3] STEREOSELECTIVE CARBON CARBON BOND FORMATION VIA ALKYLATION OF [(ETA-5-C5H5)FE(PPH3)(CO)(COME=CHR)] (R=ME,PRN,PH) - X-RAY CRYSTAL-STRUCTURE OF (Z)-[(ETA-5-C5H5)FE(PPH3)(CO)(COME=CHME)]
BAIRD, GJ
DAVIES, SG
JONES, RH
PROUT, K
WARNER, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (12) : 745 - 747
[4] ORGANOMETALLIC PHOTOELECTROCHEMISTRY - THE PHOTOOXIDATION OF AN (ARENE)CHROMIUM TRICARBONYL SYSTEM
COMPTON, RG
BARGHOUT, R
EKLUND, JC
FISHER, AC
DAVIES, SG
METZLER, MR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (01): : 39 - 42
[5] PHOTOCHEMICAL EXPULSION OF IODIDE FROM THE 1-IODOANTHRAQUINONE RADICAL-ANION
COMPTON, RG
FISHER, AC
WELLINGTON, RG
BETHELL, D
LEDERER, P
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (12) : 4749 - 4752
[6] ORGANOMETALLIC PHOTOELECTROCHEMISTRY - OXIDATION OF FAC-TRICARBONYLCHLORO[BIS(DIPHENYLPHOSPHINO)METHANE]MANGANESE(I)
COMPTON, RG
BARGHOUT, R
EKLUND, JC
FISHER, AC
BOND, AM
COLTON, R
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (08) : 1661 - 1664
[7] COMPTON RG, IN PRESS ELECTROANAL
[8] SOLUTION PHOTOSUBSTITUTION CHEMISTRY OF TRIPHENYLPHOSPHINE DERIVATIVES OF MOLYBDENUM HEXACARBONYL
DARENSBOURG, DJ
MURPHY, MA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (02) : 463 - 468
[9] PHOTOLABILISATION OF PHOSPHINE-LIGANDS BOUND TO IRON - PHOTOFRAGMENTATION VOLTAMMETRY ANALYSIS
DAVIES, SG
METZLER, MR
WATKINS, WC
COMPTON, RG
BOOTH, J
EKLUND, JC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (06): : 1005 - 1007
[10] PHOTOLABILISATION OF THE TRIPHENYLPHOSPHINE LIGAND IN THE AMINOCARBENE COMPLEX [(ETA-5-C5H5)FE(CO)(PPH3)=C(NHCH2PH)ME]+BF4-
DAVIES, SG
METZLER, MR
YANADA, K
YANADA, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (07) : 658 - 659

← 1 2 →