PHOTOLABILISATION OF PHOSPHINE-LIGANDS BOUND TO IRON - PHOTOFRAGMENTATION VOLTAMMETRY ANALYSIS

被引：5

作者：

DAVIES, SG ^{[1
]}

METZLER, MR ^{[1
]}

WATKINS, WC ^{[1
]}

COMPTON, RG ^{[1
]}

BOOTH, J ^{[1
]}

EKLUND, JC ^{[1
]}

机构：

[1] PHYS CHEM LAB,OXFORD OX1 3QZ,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 06期

关键词：

D O I：

10.1039/p29930001005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photofragmentation volammetry is used to demonstrate directly the primary loss of P(Ar)3 from [(eta5-C5H5)Fe(CO)(PAr3)=C(NHMe)Me] +BF4- (Ar = phenyl 1 and p-tolyl 2) on irradiation with visible light. In contrast, no loss of carbon monoxide is observed.

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页码：1005 / 1007

页数：3

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